DT is simply set to fire an error if you modify the D65 values it provides. When you adjust those to give a more accurate or appropriate set of coefficients to the CC module you will get a better result but you have the error simply because DT has noticed you have modified it and so it thinks you have done a double white balance for lack of a better term so don’t worry about it.
From the manual…
Chromatic adaptation is controlled within the Chromatic Adaptation Transformation (CAT) tab of the color calibration module. When used in this way the white balance module is still required as it needs to perform a basic white balance operation (connected to the input color profile values). This technical white balancing (“camera reference” mode) is a flat setting that makes grays lit by a standard D65 illuminant look achromatic, and makes the demosaicing process more accurate, but does not perform any perceptual adaptation according to the scene. The actual chromatic adaptation is then performed by the color calibration module, on top of those corrections performed by the white balance and input color profile modules. The use of custom matrices in the input color profile module is therefore discouraged. Additionally, the RGB coefficients in the white balance module need to be accurate in order for this module to work in a predictable way.
EDIT
Taken from the link I provided earlier… i think and I am not expert but basically DT is taking this approach as being the best way to handle this aspect of digital photography…